Crystal structure of bis[μ-S-hexyl 3-(2-oxidobenzylidene)dithiocarbazato-κ4 O,N 3,S:O]dicopper(II)
نویسندگان
چکیده
The title compound, [Cu2(C14H18N2OS2)2], is a binuclear copper(II) complex of an oxybenzyl-idenedi-thio-carbazate ligand. The ligand coordinates in a tridentate manner through N-, S- and O-donor atoms. Each O atom also bridges to a second Cu(II) ion to form the binuclear species. It has a central Cu2O2 rhomboid moiety and a metal-to-metal separation of 2.9923 (6) Å. In the crystal, the binuclear complexes stack along the a axis with all the hexyl chains located side-by-side, forming a hydro-phobic region. The complexes are linked via C-H⋯N hydrogen bonds, forming chains along the c-axis direction. One Cu(II) atom has the S atom of a symmetry-related complex located approximately in the apical position at 2.9740 (11) Å. This weak inter-action links the chains to form slabs parallel to the ac plane.
منابع مشابه
Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ4 O 2,N 1,S:O 2;κ4 O 2:O 2,N 1,S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate
The two Zn(II) atoms in the title compound, [Zn(2)(C(10)H(12)N(3)O(2)S)(2)Cl(2)]·3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn(2)O(2) core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydr-oxy-DMSO (DMSO is dimethyl sulfoxide) O-H⋯O ...
متن کاملBis{μ-2,2′-[(3,4-dithiahexane-1,6-diyl)bis(nitrilomethanylylidene)]bis(4-bromophenolato)-κ4 O,N,N′,O′}dicopper(II)
The crystal structure of the title compound, [Cu2(C18H12Br2N4O2S2)2], consists of binuclear complex units which lie across inversion centres and are connected by weak Cu-O coordination bonds forming chains along the b axis. The CuII ion is five-coordinated by two N atoms and two O atoms of the chelating ligand and one symmetry-related O atom forming a square-pyramidal coordination geometry. In ...
متن کاملCrystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ2 N 3,S]nickel(II)
In the title complex, [Ni(C15H21N2S2)2], the Ni(II) atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex mol-ecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant inter-actions between the aromatic rings.
متن کاملPoly[diaquadi-μ-hydroxido-κ4 O:O-dinitrato-κ4 O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]
The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octa-hedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms from a water mol-ecule, two nitrates and two hydroxides. Two Cu(II) ions are bridged by two hydroxi...
متن کاملCrystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ2 N 3,S]palladium(II)
The whole mol-ecule of the title complex, [Pd(C15H21N2S2)2], is generated by twofold rotational symmetry. The palladium(II) atom exhibits a square-planar coordination geometry, and is located on the crystallographic twofold axis that induces a cis configuration of the N,S chelating ligands. In the crystal, mol-ecules stack along the c-axis direction and there are no significant inter-molecular ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 71 شماره
صفحات -
تاریخ انتشار 2015